From Command Line:
use a space as a separator
php56 /volume1/web/PathToE!A/index.php cli/[script]

/var/packages/PHP5.6/target/usr/local/bin/php56 /volume1/web/wordpress/easy/index.php cli/waitinglist
/var/packages/PHP5.6/target/usr/local/bin/php56 /volume1/web/wordpress/easy/index.php cli/reminders
/var/packages/PHP5.6/target/usr/local/bin/php56 /volume1/web/wordpress/easy/index.php google/sync3
/var/packages/PHP5.6/target/usr/local/bin/php56 /volume1/web/wordpress/easy/index.php cli/test
/var/packages/PHP5.6/target/usr/local/bin/php56 /volume1/web/wordpress/easy/index.php cli/announcement


From crontab
Use tab as separator.  There must be a blank CR at the end of the file.
0	22	*	*	*	root	/var/packages/PHP5.6/target/usr/local/bin/php56	/volume1/web/PathToE!A/index.php cli/waitinglist
30	7	*	*	*	root	/var/packages/PHP5.6/target/usr/local/bin/php56	/volume1/web/PathToE!A/index.php cli/reminders
30	21	*	*	*	root	/var/packages/PHP5.6/target/usr/local/bin/php56	/volume1/web/PathToE!A/index.php google/sync3

Remember that different Linux installations handle crontab a little different.  Be sure to look up your system.
